▎ 摘　　要

Metal-organic frameworks (MOFs) in photocatalysis oxidation reactions have been arousing great interest because of their unique properties. Zr-based MOFs (mainly 1,4-dicarboxybenzene MOF (UiO-66)) appear to be very attractive candidates. In this study, a Pd@UiO-66/reduced graphene oxide (rGO) nanocomposite was successfully prepared via a facile solvothermal method and was characterised by several techniques, including field-emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), x-ray diffraction (XRD), nitrogen adsorption-desorption isotherms, and photoluminescence (PL) spectroscopy. Subsequently, the as-obtained Pd@UiO-66/rGO composite was used as a photocatalyst for the selective oxidation of benzyl alcohol to benzaldehyde with O-2 under visible light irradiation (>420nm); it exhibited superior photocatalytic activity due to the synergistic effect of coupling Pd nanoparticles (NPs) with UiO-66 and rGO. Importantly, the Pd@UiO-66/rGO composite showed high stability and considerable recyclability to preserve most of its initial photocatalytic activity after five cycles of the oxidation reaction.