• 文献标题:   Hydrothermal synthesis of PtRu nanoparticles supported on graphene sheets for methanol oxidation in direct methanol fuel cell
  • 文献类型:   Article
  • 作  者:   LEE SH, KAKATI N, JEE SH, MAITI J, YOON YS
  • 作者关键词:   hydrothermal method, graphene, multiwalled carbon nanotube, anodic catalyst, dmfc
  • 出版物名称:   MATERIALS LETTERS
  • ISSN:   0167-577X
  • 通讯作者地址:   Yonsei Univ
  • 被引频次:   47
  • DOI:   10.1016/j.matlet.2011.07.025
  • 出版年:   2011

▎ 摘  要

Platinum-ruthenium (PtRu) nanoparticles are dispersed on graphene nanosheets and multi-walled carbon nanotubes (MWCNTs) via a hydrothermal method. Transmission electron microsocopy (TEM) observation shows the uniformly dispersed nanoparticles and the average nanoparticle size has been calculated. The electrochemical measurements demonstrate that the Pt-Ru/graphene catalyst exhibits about two times higher mass activity and better tolerance to poisoning species in methanol electro-oxidation than the Pt-Ru/MWCNTs catalyst. This study indicates that the PtRu anodic catalyst synthesized by hydrothermal method can be applied for direct methanol fuel cells (DMFC). (C) 2011 Elsevier B.V. All rights reserved.