• 文献标题:   Nonenzymatic amperometric sensing of glucose using a glassy carbon electrode modified with a nanocomposite consisting of reduced graphene oxide decorated with Cu2O nanoclusters
  • 文献类型:   Article
  • 作  者:   MEI LP, SONG P, FENG JJ, SHEN JH, WANG W, WANG AJ, WENG XX
  • 作者关键词:   reduced graphene oxide, nanocluster, triblock copolymer, glucose, electrocatalysi
  • 出版物名称:   MICROCHIMICA ACTA
  • ISSN:   0026-3672 EI 1436-5073
  • 通讯作者地址:   Zhejiang Normal Univ
  • 被引频次:   18
  • DOI:   10.1007/s00604-015-1501-0
  • 出版年:   2015

▎ 摘  要

We describe a simple solvothermal method for preparation of reduced graphene oxide nanosheets decorated with uniform Cu2O nanoclusters by using poly(vinyl pyrrolidone)-poly(methacrylamide)-poly(vinyl imidazole) triblock co-polymer as a shape-directing agent and L-glutamic acid as a reducing agent. The resulting nanocomposite was deposited on a glassy carbon electrode where it displays improved electrocatalytic activity toward glucose oxidation in 0.5 M NaOH. This observation was exploited to construct a non-enzymatic amperometric sensor for glucose. It has a detection limit as low as 1.0 mu M, high sensitivity (23.058 mu A mM(-1)), and a dynamic (analytical) range that extends from 5.0 to 9595 mu M at a working potential of 600 mV (vs. SCE).