• 文献标题:   Graphene supported Zn2SnO4 nanoflowers with superior electrochemical performance as lithium-ion battery anode
  • 文献类型:   Article
  • 作  者:   WANG K, HUANG Y, SHEN YY, XUE LL, HUANG HJ, WU HW, WANG YL
  • 作者关键词:   zn2sno4 nanoflowers/gns composite, hydrothermal synthesi, lithiumion batterie, electrochemical propertie
  • 出版物名称:   CERAMICS INTERNATIONAL
  • ISSN:   0272-8842 EI 1873-3956
  • 通讯作者地址:   Northwestern Polytech Univ
  • 被引频次:   13
  • DOI:   10.1016/j.ceramint.2014.06.133
  • 出版年:   2014

▎ 摘  要

A hydrothermal synthesis approach has been developed to distribute the Zn2SnO4 nanoflowers on the graphene sheets (GNS). The as-prepared Zn2SnO4 nanoflowers/GNS composites were characterized by XRD, BET, FTIR, Raman, TGA, SEM, TEM and electrochemical measurements. The results show that the Zn(2)Sna(4) nanofiowers have particular 3-D structure and homogeneously adhere on graphene sheets. Electrochemical measurements suggest that Zn2SnO4 nanoflowers/GNS composites exhibit better cycling properties and lower initial irreversible capacities as anode materials for lithium-ion batteries. Galvanostatic cycling shows 1967 mAh g(-1) of initial discharge capacity and 1087 mAh g(-1) of initial charge capacity. A higher reversible capacity of 850 mAh g(-1) is obtained after 10 cycles at a current density of 300 mA g(-1). The higher reversible capacity and good stability can be ascribed to the presence of graphene. (C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.