• 文献标题:   Adsorption and removal of tetracycline antibiotics from aqueous solution by graphene oxide
  • 文献类型:   Article
  • 作  者:   GAO Y, LI Y, ZHANG L, HUANG H, HU JJ, SHAH SM, SU XG
  • 作者关键词:   graphene oxide, tetracycline, antibiotic, adsorption
  • 出版物名称:   JOURNAL OF COLLOID INTERFACE SCIENCE
  • ISSN:   0021-9797
  • 通讯作者地址:   Jilin Univ
  • 被引频次:   552
  • DOI:   10.1016/j.jcis.2011.11.015
  • 出版年:   2012

▎ 摘  要

Significant concerns have been raised over pollution of antibiotics including tetracyclines in aquatic environments in recent years. Graphene oxide (GO) is a potential effective absorbent for tetracycline antibiotics and can be used to remove them from aqueous solution. Tetracycline strongly deposited on the GO surface via pi-pi interaction and cation-pi bonding. The adsorption isotherm fits Langmuir and Temkin models well, and the theoretical maximum of adsorption capacity calculated by Langmuir model is 313 mg g(-1), which is approximately in a close agreement with the measured data. The kinetics of adsorption fits pseudo-second-order model perfectly, and it has a better rate constant of sorption (k), 0.065 g mg(-1) h(-1), than other adsorbents. The adsorption capacities of tetracycline on GO decreased with the increase in pH or Na+ concentration. The adsorption isotherms of oxytetracycline and doxycycline on GO were discussed and compared. Crown Copyright (C) 2011 Published by Elsevier Inc. All rights reserved.