• 文献标题:   The double perovskite structure effect of a novel La2CuNiO6-ZnSe-graphene nanocatalytic composite for dye sensitized solar cells as a freestanding counter electrode
  • 文献类型:   Article
  • 作  者:   OH WC, CHO KY, JUNG CH, AREEROB Y
  • 作者关键词:  
  • 出版物名称:   PHOTOCHEMICAL PHOTOBIOLOGICAL SCIENCES
  • ISSN:   1474-905X EI 1474-9092
  • 通讯作者地址:   Anhui Univ Sci Technol
  • 被引频次:   5
  • DOI:   10.1039/c8pp00487k
  • 出版年:   2019

▎ 摘  要

Currently, the development of sensitized solar cells (DSSCs) with high power conversion efficiency and low cost is a major challenge in the academic and industrial fields. In order to enhance the current efficiency of dye-sensitized solar cells (DSSCs), a perovskite graphene-La2CuNiO6-ZnSe (G-LCN-ZS) as a counter electrode (CE) was introduced in this study via a conventional microwave treatment. A DSSC with 15% G-LCN-ZS CE achieved a high-power conversion efficiency up to 11.05% under AM 1.5G solar simulation, which is one of the highest reported efficiencies for ternary oxide-based graphene DSSCs. The G-LCN-ZS CE nanocomposites exhibit excellent catalytic activity towards the I3(-)/I- redox couple due to the positive synergistic effect between LCN-ZS nanoparticles and graphene sheets. Moreover, the graphene- based materials can provide a fast diffusion pathway for the electrolyte. In this paper, we have shown that alternative materials with high energy conversion efficiency can be used in future applications.