• 文献标题:   Efficient removal of tetracycline with KOH-activated graphene from aqueous solution
  • 文献类型:   Article
  • 作  者:   MA J, SUN YR, YU F
  • 作者关键词:   tetracycline, kohactivation, adsorption, graphene, specific surface area
  • 出版物名称:   ROYAL SOCIETY OPEN SCIENCE
  • ISSN:   2054-5703
  • 通讯作者地址:   Tongji Univ
  • 被引频次:   4
  • DOI:   10.1098/rsos.170731
  • 出版年:   2017

▎ 摘  要

Activated graphene absorbents with high specific surface area (SSA) were prepared by an easy KOH-activated method, and were applied in absorbing antibiotics, such as tetracycline (TC). After activation, many micropores were introduced to graphene oxide sheets, leading to higher SSA and many new oxygen-containing functional groups, which gave KOH-ctivated graphene excellent adsorption capacity (approx. 532.59mg (g-1)) of TC. Further study on the adsorption mechanism showed that the Langmuir isotherm model and the pseudo-second-order kinetic model fitted with experiment data. To further understand the adsorption process, the effects of solid-liquid ratio, pH, ionic strength and coexisting ions were also investigated. The results revealed that, compared with pH and ionic strength, solid-liquid ratio and coexisting ions (Cu2+, CrO42-) had more significant influence over the adsorption performance. The findings provide guidance for application of KOH-activated graphene as a promising alternative adsorbent for antibiotics removal from aqueous solutions.