• 文献标题:   Graphene domain boundaries on Pt(111) as nucleation sites for Pt nanocluster formation
  • 文献类型:   Article
  • 作  者:   LIANG Z, KHOSRAVIAN H, UHL A, MEYER RJ, TRENARY M
  • 作者关键词:   platinum nanocluster, graphene, pt 111, scanning tunneling microscopy
  • 出版物名称:   SURFACE SCIENCE
  • ISSN:   0039-6028 EI 1879-2758
  • 通讯作者地址:   Univ Illinois
  • 被引频次:   17
  • DOI:   10.1016/j.susc.2012.07.005
  • 出版年:   2012

▎ 摘  要

The growth of Pt nanoclusters on a graphene layer on Pt(111) was studied with ultra high vacuum scanning tunneling microscopy. Different periodicities in the moire patterns of the graphene layer are observed corresponding to different orientations with respect to the Pt(111) lattice. Various graphene orientations are possible because of a relatively weak graphene-Pt interaction. Following Pt deposition onto the graphene-covered surface, small Pt nanoclusters are observed to preferentially form along the moire domain boundaries. The weak interaction of graphene with Pt(111) leads to a weak corrugation in the superlattice compared to other transition metals, such as Ru, but it is found even this weak corrugation is sufficient to serve as a template for the formation of mono-dispersed one-dimensional Pt nanocluster chains. These Pt nanoclusters are relatively stable and only undergo agglomeration at annealing temperatures above 600 K. (C) 2012 Elsevier B.V. All rights reserved.