▎ 摘　　要

Enhancing the nitrogen (N) doping in carbon nanomateriaLs has been suggested as an effective approach to enhance the performance of Lithium ion batteries (LIBs). However, achieving N-doped carbon nanomateriaLs with an ultrahigh N content is still a great challenge, thus Limiting the capacity enhancement. Herein, we demonstrate a new procedure for the synthesis of unique sandwich architecture of N-doped carbon/reduced graphene oxide (N-carbon/rGO) derived from simple pyrolysis of a poLypyrroLe/GO nanosheet precursor. The N-carbon/rGO exhibits the highest N-doping of 15.4% reported in all the carbon-based nanomateriaLs, and a high specific surface area of 327 m(2) g(-1) with a micro/mesoporous structure. They combine the advantages of high conductivity of rGO, very high N-fuctionalities, and the porous structure of carbons, which endow them with appealing electrochemical Lithium storage properties with a high initial reversible capacity of 1100 mA h g(-1) at 100 mA g(-1), excellent rate capability up to 20 A g(-1), and superior cycling stability over 1000 cycles at a high current density of 1 A g(-1). The present work highlights the important role of tuning the nitrogen doping in enhancing the performance of LIBs.