• 文献标题:   Influence of nitrogen on the growth of vertical graphene nanosheets under plasma
  • 文献类型:   Article
  • 作  者:   GHOSH S, POLAKI SR, KRISHNA NG, KAMRUDDIN M
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS SCIENCE
  • ISSN:   0022-2461 EI 1573-4803
  • 通讯作者地址:   Indira Gandhi Ctr Atom Res
  • 被引频次:   5
  • DOI:   10.1007/s10853-018-2080-3
  • 出版年:   2018

▎ 摘  要

We have investigated the effect of nitrogen (N-2) as a carrier gas on the growth of vertical graphene nanosheets (VGN) by plasma-enhanced chemical vapor deposition. It is demonstrated that addition of nitrogen gas with a hydrocarbon precursor can enhance the nucleation and growth rate of graphitic base layer as well as vertical sheets. Additionally, nitrogen gas can simultaneously act as an etchant as well as a dopant. Variation in the density of vertical sheets is found, and it increased initially thereafter decreased at higher nitrogen concentration. Furthermore, VGN exhibit sheet resistance from 0.89 to 1.89 K Omega/square and mobility from 8.05 to 20.14 cm(2)/V-s, depending on the morphology and type of carrier concentration. These results reveal that the surface morphology and electronic properties of VGN can be tuned by incorporation of nitrogen gas during the growth.