• 文献标题:   Ultrafast Delamination of Graphite into High-Quality Graphene Using Alternating Currents
  • 文献类型:   Article
  • 作  者:   YANG S, RICCIARDULLI AG, LIU S, DONG R, LOHE MR, BECKER A, SQUILLACI MA, SAMORI P, MULLEN K, FENG X
  • 作者关键词:   cathode material, electrochemistry, fieldeffect transistor, graphene, graphite exfoliation
  • 出版物名称:   ANGEWANDTE CHEMIEINTERNATIONAL EDITION
  • ISSN:   1433-7851 EI 1521-3773
  • 通讯作者地址:   Tech Univ Dresden
  • 被引频次:   31
  • DOI:   10.1002/anie.201702076
  • 出版年:   2017

▎ 摘  要

To bridge the gap between laboratory-scale studies and commercial applications, mass production of high quality graphene is essential. A scalable exfoliation strategy towards the production of graphene sheets is presented that has excellent yield (ca. 75%, 1-3 layers), low defect density (a C/O ratio of 21.2), great solution-processability, and outstanding electronic properties (a hole mobility of 430 cm(2) V-1 s(-1)). By applying alternating currents, dual exfoliation at both graphite electrodes enables a high production rate exceeding 20 g h(-1) in laboratory tests. As a cathode material for lithium storage, graphene-wrapped LiFePO4 particles deliver a high capacity of 167 mAh g(-1) at 1C rate after 500 cycles.