• 文献标题:   Graphene-coated pyrogenic carbon as an anode material for lithium battery
  • 文献类型:   Article
  • 作  者:   ZHANG M, GAO B, LI Y, ZHANG XW, HARDIN IR
  • 作者关键词:   graphene, pyrogenic carbon, cotton fiber, annealing, lithium battery
  • 出版物名称:   CHEMICAL ENGINEERING JOURNAL
  • ISSN:   1385-8947
  • 通讯作者地址:   Univ Florida
  • 被引频次:   10
  • DOI:   10.1016/j.cej.2013.06.025
  • 出版年:   2013

▎ 摘  要

In this work, cotton fibers and pyrene-dispersed graphene sheets were used to produce graphene-coated pyrogenic carbon as an anode material for lithium battery. The graphene sheets were wrapped around the cotton fibers by simply dipping the fabric in a graphene/pyrene-derivative suspension. And then the cotton/graphene textile was annealed at 700 degrees C in a quartz tube furnace under Ar flow conditions. During the annealing process, the gaps between separated graphene sheets were "soldered" by "glue" molecules (aromatic molecular surfactant) to form graphene-coated pyrogenic carbon. Because of the unique electric properties of the graphene "skin" on the pyrogenic carbon, the flexible graphene-coated pyrogenic carbon showed relatively large storage capacity to lithium. Galvanostatic charge-discharge experiments also showed that the graphene-coated pyrogenic carbon electrode provided a reversible discharge capacity as high as 288 mA h g(-1) even after 50 cycles and thus can be used an anode material in lithium battery. (C) 2013 Elsevier B.V. All rights reserved.