• 文献标题:   Electrochemical behavior of amaranth and its sensitive determination based on Pd-doped polyelectrolyte functionalized graphene modified electrode
  • 文献类型:   Article
  • 作  者:   GAO YD, WANG L, ZHANG YL, ZOU LN, LI GP, YE BX
  • 作者关键词:   graphene, pd np, electroanalytical, amaranth
  • 出版物名称:   TALANTA
  • ISSN:   0039-9140 EI 1873-3573
  • 通讯作者地址:   Zhengzhou Univ
  • 被引频次:   10
  • DOI:   10.1016/j.talanta.2017.03.035
  • 出版年:   2017

▎ 摘  要

In this work, poly(sodium p-styrenesulfonate) (PSS)-functionalized graphene supported palladium nanoparticles (Pd) composites were fabricated with simple ultrasonic bath method. The morphology and structure of PSS-GR-Pd composites were characterized using UV vis absorption spectra, X-ray diffraction and Transmission Electron Microscopy. By combining the merits of the PSS-GR and Pd NPs, a new electrochemical sensor was erected to detect amaranth based on the PSS-GR-Pd nanocomposites. The electrochemical behavior of amaranth was investigated systematically in 0.1 mol L-1 phosphate buffer solution (PBS 2.0). At the optimum parameter, I-pa was found to be linearly dependent on the concentrations of amaranth (1x10(-7-)x9x10(-6) mol L-1). The detection limit was 7 nM (S/N=3) and sensitivity was 5.85 mu A mu M-1. Finally, this system was utilized for determining amaranth in soft drink using the standard addition method.