• 文献标题:   Effect of Copper Substitution on the Electrocatalytic Activity of ZnMn2O4 Spinel Embedded on Reduced Graphene Oxide Nanosheet for the Oxygen Evolution Process
  • 文献类型:   Article
  • 作  者:   AMAN S, AHMAD N, MANZOOR S, ALANAZI MM, ABDELMOHSEN SAM, KHOSA RY, ALSEHEMI AG, HUA RM, ALZAHRANI HA, CHUGHTAI AH
  • 作者关键词:   zn0.4cu0.6mn2o4/rgo, hydrothermal route, ni foam, electrocatalyst, oer
  • 出版物名称:   CATALYSIS SURVEYS FROM ASIA
  • ISSN:   1571-1013 EI 1574-9266
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1007/s10563-023-09389-9 EA FEB 2023
  • 出版年:   2023

▎ 摘  要

The fabrication of a proficient and durable electrocatalyst for the OER process is the most crucial parameter in the water splitting process. A simple and basic procedure was used in this study to create Cu-substituted ZnMn2O4/rGO spinel nanosized composite as an electrode for OER. The morphological and structural investigations indicate that the carbon based spinel successfully bonds, and the addition of copper into rGO results in a substantial change in its electrocatalytic process for the oxygen evolution process. Zn1-xCuxMn2O4/rGO with x = 0.6 has a minimal overpotential of 150 mV at a current density of 10 mAcm(-2), low onset potential of 1.40 V and a smaller Tafel slope of 31 mV dec(-1) than other substitution. The electrocatalyst also exhibits high ECSA (632.5 cm(2)), R-f (1580), and exceptional stability, all of which improve OER performance. These analysis confirm the enhanced electrocatalytic efficiency of the hybrid material to catalyze OER for energy generation, and other fields.