• 文献标题:   The Correlation Between Molecular Structure and Tribological Properties of Graphene Oxide with Different Oxidation Degree
  • 文献类型:   Article
  • 作  者:   ZHAO L, YANG HM, LIU C, XUE SQ, DENG Z, LI JS, ZENG XQ
  • 作者关键词:   graphene oxide, oxidation degree, tribological propertie
  • 出版物名称:   TRIBOLOGY LETTERS
  • ISSN:   1023-8883 EI 1573-2711
  • 通讯作者地址:   Univ Chinese Acad Sci
  • 被引频次:   7
  • DOI:   10.1007/s11249-019-1199-y
  • 出版年:   2019

▎ 摘  要

Eight kinds of GOs with different oxidation degree were synthesized. Molecular structure characterization indicated that with more usage of H2SO4, less usage of KMnO4, and more reaction time at high temperatures (95 degrees C), the oxidation degree of GO decreased. Tribological tests showed that GO water suspensions could reduce the friction coefficient of water by 33-46% as well as decrease the wear rate of water by 36-64%. Lubrication mechanism verified the formation of GO tribofilms on the sliding surface. GO with higher oxidation degree had a better adsorption capacity and the optimum concentration was 0.15mg/ml. Moreover, some oxygen-containing groups of GO were decomposed to form a graphene-like structure, which would increase the tribological property of GO suspensions.