• 文献标题:   Facile synthesis of a nitrogen-doped graphene flower-like MnO2 nanocomposite and its application in supercapacitors
  • 文献类型:   Article
  • 作  者:   DONG JY, LU G, WU F, XU CX, KANG XH, CHENG ZM
  • 作者关键词:   ngmno2, hydrothermal method, specific capacitance, cycling stability
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Beijing Jiaotong Univ
  • 被引频次:   45
  • DOI:   10.1016/j.apsusc.2017.07.291
  • 出版年:   2018

▎ 摘  要

A flower-like MnO2 nanocomposite embedded in nitrogen-doped graphene (NG-MnO2) is fabricated by a hydrothermal method. It is a mesoporous nanomaterial with a pore size of approximately 0.765 cm(3) g(-1) and specific surface area of 201.8 m(2) g(-1). NG-MnO2 exhibits a superior average specific capacitance of 220 F g(-1) at 0.5 A g(-1) and a preferable capacitance of 189.1 F g(-1), even at 10 A g(-1). After 1000 cycles, over 98.3% of the original specific capacitance retention of the NG-MnO2 electrode is maintained, and it can even activate a red light emitting diode (LED) after being charged, which indicates that it has excellent cycling stability as an electrode material. This prominent electrochemical performance is primarily attributed to the nitrogen doping and mesoporous structures of NG-MnO2, which can be attributed to its numerous electroactive sites as well as faster ion and electron transfer for redox reactions than general graphene-MnO2 nanocomposites (G-MnO2). (C) 2017 Published by Elsevier B.V.