• 文献标题:   Graphene / V2O5 hybrid electrode for an asymmetric supercapacitor with high energy density in an organic electrolyte
  • 文献类型:   Review
  • 作  者:   LIU ZM, ZHANG HY, YANG Q, CHEN YW
  • 作者关键词:   aerogel, graphene, asymmetric supercapacitor, organic electrolyte
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Guangdong Univ Technol
  • 被引频次:   10
  • DOI:   10.1016/j.electacta.2018.04.212
  • 出版年:   2018

▎ 摘  要

A novel rGO/V2O5 hybrid aerogel composite made up of vanadium pentoxide nanospheres embedded in graphene sheets was synthesized by an easy hydrothermal method. V2O5 with a loading of only 12 wt% in composite played a significant pseudocapacitance role. To obtain better material, an annealing process in a tube furnace was used. The final rGO/V2O5 electrode showed excellent electrochemical performance, achieving a specific capacitance of 384 F g(-1) at 0.1 A g(-1) and of 197 F g(-1) at 2 A g(-1). The rGO/V2O5 functioned as the anode and graphene functioned as the cathode in an asymmetric supercapacitor used in an organic electrolyte resulted in a wide potential operating window of 2.5 V and delivered a maximum energy density of 80.4Wh kg(-1) (275Wkg(-1)) at 0.2 A g(-1). In addition, the device possessed acceptable cyclic stability, with only 17.8% loss after 10000 cycles at 2 A g(-1). All of these outstanding properties could make the electrode material prepared in this study a promising application material for supercapacitors. (c) 2018 Elsevier Ltd. All rights reserved.