• 文献标题:   A green hydrothermal approach for the preparation of graphene/alpha-MnO2 3D network as anode for lithium ion battery
  • 文献类型:   Article
  • 作  者:   ZHANG Y, LIU H, ZHU Z, WONG KW, MI R, MEI J, LAU WM
  • 作者关键词:   graphene, manganese dioxide nanocomposite, lithiumion battery
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   China Acad Engn Phys
  • 被引频次:   50
  • DOI:   10.1016/j.electacta.2013.07.002
  • 出版年:   2013

▎ 摘  要

Graphene/alpha-MnO2 nanocomposites (GMC) with high performance as anode material were synthesized by a facile green procedure, in which we reduced graphene from graphene oxide and prepared the GMC simultaneously through a conventional hydrothermal route. The samples are systematically investigated by X-ray diffraction analysis, Raman spectroscopy, FT-IR spectroscopy, field-emission scanning electron microscopy, and transmission electron microscopy. The GMC presents a good reversible specific capacity of 998 mAh g(-1) at a current density of 60 mA g(-1) after 30 cycles and excellent rate capabilities of 590 mAh g(-1) at a current density of 12 A g(-1). The present results indicate that GMC nanocomposites have enormous potential for application in lithium-ion batteries. (C) 2013 Elsevier Ltd. All rights reserved.