• 文献标题:   Magnetic moment centers in titanium dioxide photocatalysts loaded on reduced graphene oxide flakes
  • 文献类型:   Article
  • 作  者:   GUSKOS N, ZOLNIERKIEWICZ G, GUSKOS A, AIDINIS K, WANAG A, KUSIAKNEJMAN E, NARKIEWICZ U, MORAWSKI AW
  • 作者关键词:   magnetic oxygen defects ferromagnetic ordering system, titania nanocomposites modified with reduced graphene oxide rgo, electron paramagnetic resonance/ferromagnetic resonance
  • 出版物名称:   REVIEWS ON ADVANCED MATERIALS SCIENCE
  • ISSN:   1606-5131 EI 1605-8127
  • 通讯作者地址:  
  • 被引频次:   5
  • DOI:   10.1515/rams-2021-0012
  • 出版年:   2021

▎ 摘  要

A whole series of titania nanocomposites modified with reduced graphene oxide (rGO) was prepared using solvothermal method followed by calcination. Modification of titania with rGO has been found to lead to better photocatalytic properties. The highest photocatalytic performance was obtained at calcination temperature of 600 degrees C. Electron paramagnetic resonance/ferromagnetic resonance measurements showed oxygen defects and ferromagnetic ordering systems. The linewidth of resonance line of oxygen defects decreased linearly with calcination temperature increasing up to 600 degrees C and an accompanying growth of mean crystallite size of anatase phase. The integrated resonance line intensity of oxygen defects depended on the calcination temperature and caused a very large increase in the intensity of resonance lines originating from oxygen defects, because inert atmosphere of calcination was enhanced by graphene presence. The occurrence of magnetic ordering system significantly influenced the performance of photocatalytic processes by changing the amount of oxygen defects.