▎ 摘　　要

Oxygen evolution reaction (OER) is of great significance in electrochemical water splitting on industrial scale, which suffers from the slow kinetics and large overpotential, thus setting the main obstacle for efficient water electrolysis. To pursue cost-effective OER electrocatalysts with high activity and durable stability, we here set a facile strategy to prepare N-doped graphene supported core-shell FeNi alloy@N-doped carbon nanocages (FeNi@NC-NG) by annealing graphene oxides supported Prussian blue analogues under H-2/Ar atmosphere. Based on the specific structural benefits, the present catalyst shows superior OER catalytic activity than precious metal catalyst of RuO2 and Ir/C, with a low overpotential of 270 mV for 10 mA cm(-2), as well as high stability. The simple synthesis process and outstanding electrocatalytic performances show great potential of FeNi@NC-NG to replace the noble metal-based catalysts toward electrochemical water oxidation.