• 文献标题:   Nitrogen-doped reduced graphene oxide/MoS2 'nanoflower' composites for high-performance supercapacitors
  • 文献类型:   Article
  • 作  者:   BOKHARI SW, ELLIS AV, UCEDA M, WEI S, POPE M, ZHU S, GAO W, SHERRELL PC
  • 作者关键词:   multiphase structure, electrochemical surface area, hierarchical porosity, energy density, power density
  • 出版物名称:   JOURNAL OF ENERGY STORAGE
  • ISSN:   2352-152X EI 2352-1538
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.est.2022.105935 EA NOV 2022
  • 出版年:   2022

▎ 摘  要

Mixed-phase (MP) metal disulfides have interesting electrochemical properties which originate from the generation of the abundance of electrochemically active sites and a higher structural stability as compared with crystalline materials. However, there is less exploration in the design and performance of the MP materials for supercapacitors application. Herein, nitrogen-doped reduced graphene oxide (N-rGO) with MP molybdenum disulfide (MoS2) nanoflower (NGM) nanocomposite was self-assembled in a one-pot hydrothermal synthesis. The NGM nanocomposites featured a high surface area and electrical conductivity governed by the uniform growth of nanoflowers on the conductive N-rGO sheets. Coupled with an interconnected network of charge transport channels, the robust ion transport and lowered charge transfer resistance at the electrode-electrolyte interphase significantly boost the electrochemical activity enabling the electrodes to deliver a high specific capacitance (539.5 F g(-1)), exceptional energy and power densities (P-max = 25.4 kW kg(-1), and E-max = 71.5 Wh kg(-1)) and excellent capacitance retention of 95.3 % during long-term cycling.