• 文献标题:   Nanosized graphene crystallite induced strong magnetism in pure carbon films
  • 文献类型:   Article
  • 作  者:   WANG C, ZHANG X, DIAO DF
  • 作者关键词:  
  • 出版物名称:   NANOSCALE
  • ISSN:   2040-3364 EI 2040-3372
  • 通讯作者地址:   Shenzhen Univ
  • 被引频次:   22
  • DOI:   10.1039/c4nr06711h
  • 出版年:   2015

▎ 摘  要

We report strong magnetism in pure carbon films grown by electron irradiation assisted physical vapor deposition in electron cyclotron resonance plasma. The development of graphene nanocrystallites in the amorphous film matrix, and the dependence of the magnetic behavior on amorphous, nanocrystallite and graphite-like structures were investigated. Results were that the amorphous structure shows weak paramagnetism, graphene nanocrystallites lead to strong magnetization, and graphite-like structures corresponded with a lower magnetization. At a room temperature of 300 K, the highest saturation magnetization of 0.37 emu g(-1) was found in the nanosized graphene nanocrystallite structure. The origin of strong magnetism in nanocrystallites was ascribed to the spin magnetic moment at the graphene layer edges.