• 文献标题:   Dicarboxylic acids crosslinked graphene oxide membranes for salt solution permeation
  • 文献类型:   Article
  • 作  者:   JIA ZQ, SHI WX, WANG Y, WANG JL
  • 作者关键词:   dicarboxylic acid, crosslink, graphene oxide, membrane, salt solution permeation
  • 出版物名称:   COLLOIDS SURFACES APHYSICOCHEMICAL ENGINEERING ASPECTS
  • ISSN:   0927-7757 EI 1873-4359
  • 通讯作者地址:   Beijing Normal Univ
  • 被引频次:   14
  • DOI:   10.1016/j.colsurfa.2016.01.023
  • 出版年:   2016

▎ 摘  要

Graphene oxide (GO) membranes were crosslinked by dicarboxylic acids in order to improve the mechanical strength, stability and permeation performance. The effects of crosslinking conditions (temperature, catalyst concentration, time, crosslinker concentration) on the mechanical performance, along with the influences of crosslinker molecular structure on the thermal stability and swelling degree of GO membranes, were studied. The thermal pyrolysis temperature of crosslinked GO membranes increased about 2-8 degrees C while the swelling degree averagely decreased about 66% in DI water and 40% in 0.05 mol L-1 of KCl solution in comparison with those of pristine one. In the permeation of single salt solutions, the fluxes are positively correlated to the swelling degree of GO membranes. The effects of swelling degree on the permeation fluxes were firstly noticed. The crosslinked GO membranes show high permeation fluxes (more than 2 times) along with low swelling degree, demonstrating its potential application in ion dialysis. (C) 2016 Elsevier B.V. All rights reserved.