• 文献标题:   Highly sensitive electrochemical sensor for the food toxicant Sudan I based on a glassy carbon electrode modified with reduced graphene oxide decorated with Ag-Cu nanoparticles
  • 文献类型:   Article
  • 作  者:   YAO YZ, LIU YC, YANG ZS
  • 作者关键词:   nanomaterial, synergistic electron transfer, amperometry, trace determination
  • 出版物名称:   MICROCHIMICA ACTA
  • ISSN:   0026-3672 EI 1436-5073
  • 通讯作者地址:   Anhui Normal Univ
  • 被引频次:   6
  • DOI:   10.1007/s00604-016-1977-2
  • 出版年:   2016

▎ 摘  要

The authors describe a method for room temperature preparation of reduced graphene oxide (rGO) decorated with Ag-Cu nanoparticles (NPs). The nanocomposite (Ag-CuNP/rGO) was characterized by scanning electron microscopy, energy dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy and transmission electron microscopy. A glassy carbon electrode (GCE) modified with this nanocomposite dispersed is shown to be a viable electrode for determination of Sudan I (best at a working voltage of -112 mV vs. Ag/AgCl), with remarkably increased electrochemical response to Sudan I compared to that of a plain GCE. The calibration plot is linear in the 1.0 nM to 10 A mu M concentration range, with a 0.4 nM detection limit (at a signal-to-noise ratio of 3). The method was successfully applied to the determination of Sudan I in ketchup and chili powder.