• 文献标题:   Optimization of Electrochemical Performance for Activated Carbon and Functionalized Graphene Composite-Based Supercapacitor
  • 文献类型:   Article
  • 作  者:   LEE KS, JEONG HT
  • 作者关键词:   activated carbon, compatibility, functionalized reduced graphene oxide, reduced graphene oxide, supercapacitor, wettability
  • 出版物名称:   JOURNAL OF MATERIALS ENGINEERING PERFORMANCE
  • ISSN:   1059-9495 EI 1544-1024
  • 通讯作者地址:  
  • 被引频次:   3
  • DOI:   10.1007/s11665-022-06598-7 EA JAN 2022
  • 出版年:   2022

▎ 摘  要

In this paper, we optimize the ratio of activated carbon (AC) and reduced graphene oxide (rGO) to fabricate their composite to improve the electrochemical performances of the rGO/AC composite-based supercapacitor. In addition, the rGO is functionalized by using an ionic liquid (F-rGO) as 1-ethyl-3-methylimidazolium tetrafluoroborate (EMIBF4) to enhance wettability and compatibility between electrode and electrolyte. The electrochemical performances of F-rGO and AC (F-rGO/AC-15) composite-based supercapacitor are evaluated by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and galvanostatic charge/discharge tests (GCD). The F-rGO/AC-15 composite (15:85, w/w %)-based supercapacitor indicates low charge transfer resistance (0.41 omega) when compares to the rGO/AC-15 composite-based supercapacitor (0.6 omega). In addition, F-rGO/AC-15 composite-based supercapacitor shows high energy density of 146 Wh kg(-1), while pristine AC-based supercapacitor showed energy density of 50.1 Wh kg(-1) with 416.6 W kg(-1) of power density. The F-rGO/AC-15 composite-based supercapacitor also shows the enhanced specific capacitance of 127 F g(-1).