• 文献标题:   Enhanced electrical and thermal conductivities of 3D-SiC(rGO, Gx) PDCs based on polycarbosilane-vinyltriethoxysilane-graphene oxide (PCS-VTES-GO) precursor containing graphene fillers
  • 文献类型:   Article
  • 作  者:   HAN YC, ZHONG L, ZHENG YN, ZHOU R, LIAO L, CHEN GL, HUANG WY, LIN SY, ZHONG YJ, LI JB, ZHENG W, YAO RQ
  • 作者关键词:   sic, polycarbosilane, graphene, electrical conductivity, polymerderived ceramic
  • 出版物名称:   CERAMICS INTERNATIONAL
  • ISSN:   0272-8842 EI 1873-3956
  • 通讯作者地址:   Xiamen Univ
  • 被引频次:   2
  • DOI:   10.1016/j.ceramint.2019.09.056
  • 出版年:   2020

▎ 摘  要

Lightweight 3D-SiC(rGO, Gx) PDCs were fabricated from polycarbosilane-vinyltriethoxysilane-graphene oxide (PCS-VTES-GO) precursor added by different amounts of graphene fillers via direct cold molding and pyrolysis at 1400 degrees C in an easy manner. Results reveal that SiC(rGO, Gx) PDCs consist of beta-SiC nanocrystals homogeneously embedded within amorphous SiOxCy/C-free and graphene is well compatible with SiOxCy/C-free for void-free bonded interface, efficiently delaying decomposition of SiOxCy phase into beta-SiC. The nanocomposite structure provides an ingenious strategy for constructing complexes with good integrity, high ceramic yield, excellent thermal stability, high electrical and thermal conductivities. This improvement is primarily attributed to the presence of graphene with considerably increasing electric-charge carriers and wider phonon-channel. Such 3D-SiC(rGO, G(20%)) PDCs possess satisfying hardness (12.02 GPa), high electrical conductivity (23.82 S cm(-1)) and thermal conductivity (7.47 W m(-1)K(-1)), which make them attractive candidates for microelectromechanical systems (MEMS) devices, energy storage/conversion systems and high precision components, etc.