• 文献标题:   Direct Z-scheme photocatalytic removal of ammonia via the narrow band gap MoS2/N-doped graphene hybrid catalyst upon near-infrared irradiation
  • 文献类型:   Article
  • 作  者:   ZHANG H, GU QQ, ZHOU YW, LIU SQ, LIU WX, LUO L, MENG ZD
  • 作者关键词:   mos2/ndoped graphene, narrow band gap, zscheme photocatalysi, degradation ammonia, nearinfrared irradiation
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Suzhou Univ Sci Technol
  • 被引频次:   4
  • DOI:   10.1016/j.apsusc.2019.144065
  • 出版年:   2020

▎ 摘  要

Near-infrared (NIR) irradiation accounts for approximately 54.3% of the solar spectrum. Therefore, MoS2 and N-doped graphene (NG) were utilised to fabricate a direct Z-scheme NIR-response photocatalytic system (MoS2/NG). The photocatalytic tests showed that MoS2/NG Z-scheme photocatalytic system can result in a 99.6% degradation ratio of ammonia under NIR irradiation, whereas the removal ratio of ammonia was only 64.0% using MoS2 as the photocatalyst under similar conditions. The catalytic efficiency is still over 90.7% even if the MoS2/NG catalyst was used for five runs, indicating that it is extremely stable. The kinetic research indicated the average apparent rate constant k(app) for ammonia degradation into N-2 was at approximately 0.251 h(-1). The enhanced photocatalytic activity of MoS2/NG was attributed to the more positive valence band level of the Z-scheme system.