• 文献标题:   A Facile Route To Recover Intrinsic Graphene over Large Scale
  • 文献类型:   Article
  • 作  者:   SHIN DW, LEE HM, YU SM, LIM KS, JUNG JH, KIM MK, KIM SW, HAN JH, RUOFF RS, YOO JB
  • 作者关键词:   graphene, transistor, intrinsic propertie, buffed oxide etch boe, pmma, h2o/o2 redox system, fermi level
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851
  • 通讯作者地址:   Sungkyunkwan Univ
  • 被引频次:   56
  • DOI:   10.1021/nn3017603
  • 出版年:   2012

▎ 摘  要

The intrinsic properties of initially p-type doped graphene (grown by chemical vapor deposition (CVD)) can be recovered by buffered oxide etch (BOE) treatment, and the dominant factor governing p-type doping is identified as the H2O/O-2 redox system. Semi-ionic C-F bonding prevents the reaction between the products of the H2O/O-2 redox system and graphene. BOE-treated graphene field effect transistors (FETs) subsequently exposed to air, became p-type doped due to recovery of the H2O/O-2 redox system. In comparison, poly(methyl methacrylate) (PMMA)-coated graphene FETs had improved stability for maintaining the intrinsic graphene electronic properties.