• 文献标题:   Synthesis of TiO2-Reduced Graphene Oxide Nanocomposites Offering Highly Enhanced Photocatalytic Activity
  • 文献类型:   Article
  • 作  者:   LI WF, YANG XH, FU HT, AN XZ, ZHAO HY
  • 作者关键词:   graphene, titanium dioxide, nanocomposite, hydrothermal, photocatalysi
  • 出版物名称:   JOURNAL OF NANOSCIENCE NANOTECHNOLOGY
  • ISSN:   1533-4880 EI 1533-4899
  • 通讯作者地址:   Northeastern Univ
  • 被引频次:   1
  • DOI:   10.1166/jnn.2019.16624
  • 出版年:   2019

▎ 摘  要

Photogenerated electron-hole recombination significantly restricts the catalytic efficiency of titanium dioxide (TiO2). Various approaches have been developed to overcome this problem, yet it remains challenging. Recently, graphene modification of TiO2 has been considered as an effective alternative to prevent electron-hole recombination and consequently enhance the photocatalytic performance of TiO2. This study reports an efficient but simple hydrothermal method utilizing titanium (IV) butoxide (TBT) and graphene oxide (GO) to prepare TiO2-reduced graphene oxide (RGO) nanocomposites under mild reaction conditions. This method possesses several advantageous features, including no requirement of high temperature for TiO2 crystallization and a one-step hydrothermal reaction for mild reduction of GO without a reducing agent, which consequently makes the production of TiO2-RGO nanocomposites possible in a green and an efficient synthetic route. Moreover, the as-synthesized nanocomposites were characterized by numerous advanced techniques (SEM, TEM, BET, XRD, XPS, and UV-vis spectroscopy). In particular, the photocatalytic activities of the synthesized TiO2-RGO nanocomposites were evaluated by degrading the organic molecules (methylene blue, MB), and it was found that the photocatalytic activity of TiO2-RGO nanocomposites is similar to 4.5 times higher compared to that of pure TiO2. These findings would be useful for designing reduced graphene oxide-metal oxide hybrids with desirable functionalities in various applications for energy storage devices and environmental remediation.