• 文献标题:   Copper complex with N-,O- architecture grafted graphene oxide nanosheet as a heterogeneous catalyst for Suzuki cross coupling reaction
  • 文献类型:   Article
  • 作  者:   ANUMA S, MISHRA P, BHAT BR
  • 作者关键词:   schiff base, amino functionalized graphene oxide, heterogenous catalyst, suzuki cross coupling
  • 出版物名称:   JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
  • ISSN:   1876-1070 EI 1876-1089
  • 通讯作者地址:   Natl Inst Technol Karnataka
  • 被引频次:   8
  • DOI:   10.1016/j.jtice.2018.09.029
  • 出版年:   2019

▎ 摘  要

We report a straight forward synthesis of a heterogeneous catalyst by covalently immobilizing copper Schiff base complex on the surface of amino functionalized graphene oxide (AGO) for the Suzuki coupling of substituted aryl halides with arylboronic acids. The as-synthesized complex and subsequent catalyst were characterized for their structural features using suitable techniques. The analysis confirmed that the Cu bound to Schiff base (L) ligand via bi(N-,O-) linkage and Cu-L immobilization on AGO was due to its amino functionality. The catalyst exhibited excellent yield of 94% for Suzuki coupling reactions as analyzed by gas chromatography. The catalyst was recycled for 5 successive reactions with insignificant loss in efficiency. ICP-AES analysis showed the catalyst retained 87.5% of its active metal center after 5th iteration. High yield, environmentally benign, easy work-up procedure, easy separation of catalyst and mild reaction conditions are some of the important facets this catalyst offer. (C) 2018 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.