▎ 摘　　要

In this paper, the graphene in situ coated Co3O4 core-shell heterogeneous composites have been facilely fabricated via microwave plasma-enhanced chemical vapor deposition method. The graphene thin-shell-layer-covered Co3O4-x particles were revealed by FE-SEM, XRD, XPS and Raman spectra. And the ratio of Co2+/Co3+ is adjusted, and abundant surface oxygen vacancies are created by the microwave plasma etching, which can contribute to the improvement of electrochemical performance for the Co3O4/graphene core-shell composites. Results present that the graphene in situ coated Co3O4-x has a specific capacitance of 192.8 F g(-1) under the current density of 0.5 A g(-1), which is 4.5 times than that of the original Co3O4 sphere. Meanwhile, the core-shell heterogeneous composite displays excellent cyclic stability with 98.5% specific capacitance retained after 20,000 cycle tests.