• 文献标题:   Nitrogen-Doped Graphene Nanosheets/S Composites as Cathode in Room-Temperature Sodium-Sulfur Batteries
  • 文献类型:   Article
  • 作  者:   HAO Y, LI XF, SUN XL, WANG CL
  • 作者关键词:   cathode, ndoped graphene, nanocomposite, roomtemperature nas batterie, sulfur
  • 出版物名称:   CHEMISTRYSELECT
  • ISSN:   2365-6549
  • 通讯作者地址:   Florida Int Univ
  • 被引频次:   9
  • DOI:   10.1002/slct.201701951
  • 出版年:   2017

▎ 摘  要

Room-temperature sodium-sulfur (RT Na-S) batteries have gained increasing attention from energy storage community in recent years. In this work, homogeneous nitrogen-doped graphene nanosheets/sulfur (NGNS/S) nanocomposites, synthesized using chemical reaction-deposition method and low temperature heat treatment, were studied as active cathode materials for RT Na-S batteries. Different loading composites with 86%, 65%, 45% and 25% gamma-S-8 have been electrochemically evaluated, respectively, and compared with two control electrodes of NGNS and S. It was found that the NGNS/S composite with 25% S loading exhibited the best electrochemical performance with specific capacities of 212 and 136 mAh g(-1) in the 1st and 10th cycles, respectively. The enhanced electrochemical performance of NGNS/S nanocomposite is mainly attributed to the improved kinetics due to the NGNS conductive network and easier intercalation of Na+ into expanded NGNS layers due to the addition of S within the graphene layers. In addition, the composite with 25% S loading shows higher surface area and complete reaction with product of Na2S, which likely contributes to the improved energy capacity.