• 文献标题:   The role of solvent on the formulation of graphene/polyporphyrin hybrid material versus photocatalytic activity
  • 文献类型:   Article
  • 作  者:   USSIA M, RUFFINO F, BRUNO E, SPINA E, CONTICELLO I, PRIVITERA V, CARROCCIO SC
  • 作者关键词:  
  • 出版物名称:   POLYMER BULLETIN
  • ISSN:   0170-0839 EI 1436-2449
  • 通讯作者地址:   Univ Catania
  • 被引频次:   2
  • DOI:   10.1007/s00289-019-02849-1
  • 出版年:   2020

▎ 摘  要

The influence of solvent used to prepare hybrid materials for photocatalytic applications formulated by cyclic bisphenol A/porphyrin copolyformal and graphene is here reported. To this purpose, the polymer is dissolved in different solvents [chloroform, tetrahydrofuran and dimethylformamide (DMF)] and used to impregnate via bath deposition 2D graphene. Depending on the nature of the solvent, polymer coats differently the graphene substrates producing peculiar SEM and AFM data. Microscopic and nanoscopic features of formulated materials were correlated with their photocatalytic activities by using methylene blue degradation test. Data collected under visible-light irradiation reveal as the best photodegradation performance was displayed by graphene coated with DMF copolyporphyrin solution. [GRAPHICS]