• 文献标题:   Graphene Nanoribbon/V2O5 Cathodes in Lithium-Ion Batteries
  • 文献类型:   Article
  • 作  者:   YANG Y, LI L, FEI HL, PENG ZW, RUAN GD, TOUR JM
  • 作者关键词:   graphene nanoribbon, v2o5, lithium ion batterie, cathode, cyclability
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244
  • 通讯作者地址:   Rice Univ
  • 被引频次:   63
  • DOI:   10.1021/am501969m
  • 出版年:   2014

▎ 摘  要

Nanocrystalline V2O5 particles were successfully entrapped by graphene nanoribbons (GNRs) derived from unzipped carbon nanotubes. The electrical conductivity of V2O5 nanoparticles was enhanced after introducing the GNRs. The 3-dimensional conductive framework in the composites plays a significant role in improving the rate performance and cyclability of the material when used as a cathode in lithium-ion batteries. By tailoring the mass ratio between the GNRs and the V2O5 nanoparticles, the fabricated composites can deliver a high capacity of 278 mAh g(-1) at 0.1 C, which is close to its theoretical value, whereas a capacity of 165 mAh g(-1) can be maintained at 2 C. The delivered capacity at 0.1 C can maintain 78% of its initial capacity after 100 cycles.