• 文献标题:   Barium (II)-doped zinc ferrite. reduced graphene oxide nanohybrids for superior adsorption and magnetic properties
  • 文献类型:   Article
  • 作  者:   FEI P, QIAO J, HUO JX, LIU JH, ZHONG M, SU BT
  • 作者关键词:   barium ion doped zinc ferrite/reduced graphene oxide, onepot solvothermal method, magnetic property, adsorption activity
  • 出版物名称:   NEW CARBON MATERIALS
  • ISSN:   1007-8827 EI 1872-5805
  • 通讯作者地址:   Northwest Normal Univ
  • 被引频次:   3
  • DOI:   10.1016/S1872-5805(17)60131-8
  • 出版年:   2017

▎ 摘  要

A one-step solvothermal method was used to prepare barium (II)-doped zinc ferrite/reduced graphene oxide (Ba2+-ZF/rGO) magnetic nanohybrid adsorbents-During the solvothermal treatment, Ba2+-ZF nanoparticles were formed from Ba2+, Fe3+ and Zn2+ chlorides, which were anchored on the surface of rGO obtained from the reduction of GO with ethylene glycol-TEM and SEM results show that the Ba2+-ZF nanoparticles are uniformly distributed on the rGO sheets without any agglomeration. When used as adsorbents, the Ba2+-ZF/rGO nanohybrid with an rGO content of 35% possesses excellent adsorption capacities for methylene blue at different initial concentrations and the adsorption kinetics can be well-described by the pseudo-second-order kinetic model. The formation of Fe2+ from FeCl3 center dot 6H(2)O and the doping of Ba2+ into the spinel structure dramatically improve the magnetism of the zinc ferrite, which makes the magnetic separability of the nanohybrid outstanding. The Ba2+-ZF/rGO nanohybrid could be used as an efficient, magnetically separable adsorbent for removing organic dyes.