• 文献标题:   Environmentally Friendly Reduction of Graphene Oxide Using Tyrosine for Nonenzymatic Amperometric H2O2 Detection
  • 文献类型:   Article
  • 作  者:   WANG Q, LI MS, SZUNERITS S, BOUKHERROUB R
  • 作者关键词:   reduced graphene oxide, tyrosine, nonenzymatic, hydrogen peroxide, amperometric detection
  • 出版物名称:   ELECTROANALYSIS
  • ISSN:   1040-0397 EI 1521-4109
  • 通讯作者地址:   Univ Lille 1
  • 被引频次:   20
  • DOI:   10.1002/elan.201300356
  • 出版年:   2014

▎ 摘  要

Herein, we report on the simultaneous reduction and functionalization of graphene oxide (GO) with environmentally friendly tyrosine through the direct reaction of GO with tyrosine (Tyr) at 100 degrees C for 24 h. The resultant material (rGO/Tyr) has been characterized using UV-vis spectrometry, FTIR spectroscopy, X-ray photoelectron spectroscopy (XPS), and electrochemical measurements. The rGO/Tyr nanomaterial displayed good electrocatalytic activity for the detection of hydrogen peroxide (H2O2) with a wide linear range from 100 mu M to 2.1 mM, a detection limit of 80 mM and a sensitivity of 69.07 mu AmM-1 cm(-2). In addition, the rGO/Tyr electrode showed good selectivity for H2O2 detection in the presence of uric acid, ascorbic acid, dopamine and glucose.