• 文献标题:   Spatial-Interleaving Graphene Supercapacitor with High Area Energy Density and Mechanical Flexibility
  • 文献类型:   Article, Early Access
  • 作  者:   WANG LF, YAO HZ, CHI FY, YAN JF, CHENG HH, LI Y, JIANG L, QU LT
  • 作者关键词:   supercapacitor, graphene, areal energy density, structure configuration, laser, flexible
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1021/acsnana.2c04989 EA AUG 2022
  • 出版年:   2022

▎ 摘  要

The booming portable electronics market has raised huge demands for the development of supercapacitors with mechanical flexibility and high power density in the finite area; however, this is still unsatisfied by the currently thickness-confined sandwich design or the inplane interdigital configuration with limited mechanical features. Here, a spatial-interleaving supercapacitor (SI-SC) is first designed and constructed, in which the graphene microelectrodes are reversely stacked layer by layer within a three-dimensional (3D) space. Because each microelectrode matches well with four counter microelectrodes and all 3D spatial-interleaving microelectrodes have narrow interspaces that maintain the efficient ions transport in the whole device, this SI-SC has a prominent liner capacitance increase along with the device thickness. As a result, the high specific areal capacitance of 36.46 mF cm(-2) and 5.34 mu Wh cm(-2) energy density is achieved on the 100 mu m thick device. Especially, the microelectrodes in each layer are interdigitated, ensuring the outstanding mechanical flexibility of SI-SC, with similar to 98.7% performance retention after 10(4) cycles of bending tests, realizing the excellent integration of high area energy density and mechanical flexibility in the finite area. Furthermore, the SI-SC units can be easily integrated into wearable electronics to power wristwatches, light-emitting diodes (LEDs), calculators, and so on for practical applications.