• 文献标题:   Synthesis of graphene oxide/rare-earth complex hybrid luminescent materials via pi-pi stacking and their pH-dependent luminescence
  • 文献类型:   Article
  • 作  者:   ZHAO YC, HUANG LJ, WANG YX, TANG JG, WANG Y, LIU JX, BELFIORE LA, KIPPER MJ
  • 作者关键词:   graphene oxide, rareearth, luminescence, phdependent
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Qingdao Univ
  • 被引频次:   17
  • DOI:   10.1016/j.jallcom.2016.06.100
  • 出版年:   2016

▎ 摘  要

2-Thenoyltrifluoroacetone (Tta) and 1,10-Phenanthroline hydrate (Phen) were used as ligands for Eu3+ ions to prepare graphene oxide (GO)/rare-earth (RE) complex hybrid luminescent materials by a new method. The as-prepared products are characterized via fluorescence microscopy, transmission electron microscopy, Fourier-transform infrared spectroscopy, UV-Vis absorption spectroscopy, X-ray diffraction, fluorescence spectroscopy, and thermogravimetric analysis. The hybrid materials exhibit good solubility, long luminescent lifetime, high fluorescence quantum yield, good thermal and photo stability. Moreover, their fluorescence properties in sodium acetate/acetic acid buffer solution over the pH range from 3.6 to 5.4 are also studied. These properties of hybrid materials provide an important basis for their application in medicine, as potential biological markers, and as drug delivery vehicles. (C) 2016 Elsevier B.V. All rights reserved.