• 文献标题:   The influence of graphene/carbon mass ratio on microstructure and electrochemical behavior in the graphene-SnO2-carbon composite as anodes for Li-ion batteries
  • 文献类型:   Article
  • 作  者:   LU X, YANG F, WANG Y, GENG X, XIAO P
  • 作者关键词:   liion battery, tin dioxide, graphene, amorphous carbon
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Univ Manchester
  • 被引频次:   16
  • DOI:   10.1016/j.jallcom.2015.02.160
  • 出版年:   2015

▎ 摘  要

This paper reports a simplified one-step hydrothermal approach to prepare the graphene-SnO2-amorphous carbon (Gr-SnO2-C) composites which have a fixed SnO2 content and various graphene to amorphous carbon (Gr/C) mass ratio as anode for Li-ion batteries. The Gr-SnO2-C with a Gr/C mass ratio of 1:4 shows the best cycling stability at a current density of 300 mA g(-1). Then, at a low current density of 50 mA g(-1), it reveals a reversible capacity of around 878 mA h g(-1) after 50 cycles. By studying the microstructure evolution and electrochemical performance as a function of the Gr/C mass ratio, it is discovered that the Gr/C mass ratio can affect the Gr-SnO2-C composites in the aspects of porous structures, conductivity of active materials and microstructural stability. The enhanced performance of the Gr-SnO2-C composites is attributed to the synergism between the graphene, amorphous carbon and SnO2 nanoparticles. (C) 2015 Elsevier B.V. All rights reserved.