• 文献标题:   Temperature Dependence of G and D' Phonons in Monolayer to Few-Layer Graphene with Vacancies
  • 文献类型:   Article
  • 作  者:   YANG MM, WANG LL, QIAO XF, LIU Y, LIU YF, SHI YF, WU HL, LIANG BL, LI XL, ZHAO XH
  • 作者关键词:   defect, raman spectra, temperature dependence, thickness dependence
  • 出版物名称:   NANOSCALE RESEARCH LETTERS
  • ISSN:   1931-7573 EI 1556-276X
  • 通讯作者地址:   Hebei Univ
  • 被引频次:   0
  • DOI:   10.1186/s11671-020-03414-w
  • 出版年:   2020

▎ 摘  要

The defects into the hexagonal network of a sp(2)-hybridized carbon atom have been demonstrated to have a significant influence on intrinsic properties of graphene systems. In this paper, we presented a study of temperature-dependent Raman spectra of G peak and D' band at low temperatures from 78 to 318 K in defective monolayer to few-layer graphene induced by ion C+ bombardment under the determination of vacancy uniformity. Defects lead to the increase of the negative temperature coefficient of G peak, with a value almost identical to that of D' band. However, the variation of frequency and linewidth of G peak with layer number is contrary to D' band. It derives from the related electron-phonon interaction in G and D' phonon in the disorder-induced Raman scattering process. Our results are helpful to understand the mechanism of temperature-dependent phonons in graphene-based materials and provide valuable information on thermal properties of defects for the application of graphene-based devices.