• 文献标题:   Graphene mediated growth of polycrystalline indium phosphide nanowires and monocrystalline-core, polycrystalline-shell silicon nanowires on copper
  • 文献类型:   Article
  • 作  者:   NORRIS KJ, GARRETT M, COLEMAN E, TOMPA GS, ZHANG J, KOBAYASHI NP
  • 作者关键词:   nanowirc, mocvd, polycrystalline, indium phosphide, silicon, copper, graphene
  • 出版物名称:   JOURNAL OF CRYSTAL GROWTH
  • ISSN:   0022-0248 EI 1873-5002
  • 通讯作者地址:   Univ Calif Santa Cruz
  • 被引频次:   5
  • DOI:   10.1016/j.jcrysgro.2014.08.016
  • 出版年:   2014

▎ 摘  要

Two types of semiconductors, indium phosphide (InP) and silicon (Si), were separately grown on polycrystalline copper foils with the presence of gold colloidal particles. InP was grown with and without carbon deposition by metal organic chemical vapor deposition, and Si was grown with and without plasma enhanced chemical vapor deposition of carbon. While lnP and Si grew as films on untreated copper foils, they were found to grow in the form of nanowires when copper foils were pre-treated with carbon. Structural analysis revealed that the grown lnP nanowires were polycrystalline. In contrast, the grown Si nanowires were found to have core-shell structures with a monocrystalline core and a polycrystalline shell. Further analysis suggested that graphene was formed on the copper foils during the carbon deposition. Therefore, we concluded that the presence of graphene promoted the growth of lnP and Si in the form of nanowires. The demonstration of growing semiconductor nanowires on copper foils could be a new path to integrate semiconductor and metal to provide a unique material platform for a wide range of devices. (C) 2014 Elsevier B.V. All rights reserved.