• 文献标题:   Graphene-titania films by supersonic kinetic spraying for enhanced performance of dye-sensitized solar cells
  • 文献类型:   Article
  • 作  者:   KIM DY, JOSHI BN, PARK JJ, LEE JG, CHA YH, SEONG TY, NOH SI, AHN HJ, ALDEYABE SS, YOON SS
  • 作者关键词:   graphenetitania, dyesensitized solar cell, aerosol deposition, supersonic kinetic spraying
  • 出版物名称:   CERAMICS INTERNATIONAL
  • ISSN:   0272-8842 EI 1873-3956
  • 通讯作者地址:   Korea Univ
  • 被引频次:   22
  • DOI:   10.1016/j.ceramint.2014.03.131
  • 出版年:   2014

▎ 摘  要

Graphene-titania films were fabricated by supersonic kinetic spray, known as aerosol deposition. Graphene concentration was varied to fabricate 0.1, 0.3, 0.5, 0.7, and 1.0 wt% G-TiO2 films for dye-sensitized solar cell (DSSC) application and to investigate the effect of graphene concentration on their energy conversion efficiency. The G TiO2 films were characterized and analyzed based on results from SEM, XRD, XPS, TEM, and the current-voltage curve. The optimal concentration was 0.3 wt%, which decreased the recombination rate, favoring the formation of photogenerated electron-hole pairs. As a result, the conversion efficiency was 5.02% while that of the pure TiO2 was 3.14%. A clear trend per various concentrations was observed. At higher concentrations than 0.3 wt%, the conversion efficiency decreased owing to higher absorption of light by graphene present on the surface, thus reducing the generation of electron-hole pairs. (C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.