• 文献标题:   Highly loaded CoO/graphene nanocomposites as lithium-ion anodes with superior reversible capacity
  • 文献类型:   Article
  • 作  者:   QI Y, ZHANG H, DU N, YANG DR
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488
  • 通讯作者地址:   Zhejiang Univ
  • 被引频次:   80
  • DOI:   10.1039/c2ta00929c
  • 出版年:   2013

▎ 摘  要

This paper reports a facile approach for the synthesis of highly loaded CoO/graphene nanocomposites in an oil-phase solution with Co(acac)(3) as the cobalt precursor. Based on a thermal decomposition process, octahedral CoO nanocrystals (NCs) with a high density were homogeneously anchored onto the graphene nanosheets. These as-prepared graphene based nanocomposites with a high loading of CoO NCs exhibited superior electrochemical properties as anode materials for lithium-ion batteries, including a large reversible capacity, excellent cyclic performance, and high rate capability. Their robust composite structures, large quantity of accessible active sites, and synergistic effects between CoO NCs and graphene may be responsible for the substantially enhanced performance.