• 文献标题:   Shungite-derived graphene as a carbon support for bifunctional oxygen electrocatalysts
  • 文献类型:   Article
  • 作  者:   KAZIMOVA N, PING KF, ALAM M, DANILSON M, MERISALU M, ARUVALI J, PAISTE P, KAARIK M, MIKLI V, LEIS J, TAMMEVESKI K, STARKOV P, KONGI N
  • 作者关键词:   shungite, carbon support, bifunctional electrocatalyst, nitrogen doping, renewable energy, orr, oer
  • 出版物名称:   JOURNAL OF CATALYSIS
  • ISSN:   0021-9517 EI 1090-2694
  • 通讯作者地址:  
  • 被引频次:   9
  • DOI:   10.1016/j.jcat.2021.01.004 EA JAN 2021
  • 出版年:   2021

▎ 摘  要

Metal-air batteries (MABs) and regenerative fuel cells (RFCs) technologies rely on a combination of effi-cient electrochemical oxygen evolution and oxygen reduction reactions (OER and ORR, respectively). However, such bifunctional oxygen electrocatalysts also rely on the use of readily accessible carbon sup-ports. Herein, we show that shungite, a natural mineral, can serve as an efficient support for development of bifunctional electrocatalysts. Namely, we purify the mineral to remove additional metals and screen various combinations of cobalt, iron and nitrogen sources to identify electrochemically most suitable sys-tem to serve as an active bifunctional oxygen electrocatalyst material. (c) 2021 Elsevier Inc. All rights reserved.