• 文献标题:   FeOx and Si nano-dots as dual Li-storage centers bonded with graphene for high performance lithium ion batteries
  • 文献类型:   Article
  • 作  者:   YANG J, ZHENG J, HU L, TAN R, WANG K, MU SC, PAN F
  • 作者关键词:  
  • 出版物名称:   NANOSCALE
  • ISSN:   2040-3364 EI 2040-3372
  • 通讯作者地址:   Wuhan Univ Technol
  • 被引频次:   7
  • DOI:   10.1039/c5nr03311j
  • 出版年:   2015

▎ 摘  要

A novel design based on both FeOx and Si nano-dots bonded with graphene (FeOx center dot Si@GNS) as dual lithium-storage centers is reported. They show high performance as anode materials for Li-ion batteries with a remarkable reversible capacity of 1160 mA h g(-1) at 0.2 A g(-1), fast charging/discharging rate, and long cycling life (e.g., a capacity retention of 81.7% at 2.0 A g(-1) after 600 cycles). The origin of these high performances comes from the key factors of the high theoretical specific capacity of FeOx and Si, the shorter Li-ion diffusion distance of both nano-dot structures, fast electron conductivity, and the strain relaxation due to volume variations of both nano-dots bonded with graphene nanosheets during cycles.