• 文献标题:   Catalyst-free approach for growth of graphene sheets on high-density silica nanowires by CVD
  • 文献类型:   Article
  • 作  者:   WANG ZW, XUE ZY, WANG G, DAI JY, ZHENG XH, MA J, LI YH, ZHANG M
  • 作者关键词:   graphene, silica nanowire, chemical vapor deposition, carbon material
  • 出版物名称:   MATERIALS LETTERS
  • ISSN:   0167-577X EI 1873-4979
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   5
  • DOI:   10.1016/j.matlet.2015.10.022
  • 出版年:   2016

▎ 摘  要

A novel "two-step annealing" method is proposed for the direct synthesis of graphene sheets on high-density dielectric silica nanowires without using metal catalysts. During the first annealing at 1000 degrees C, the extremely thin SiO2 layer on Si substrate shrinks and forms dense nanoparticles. Using these silica nanoparticles as templates, graphene sheets and silica nanowires are synthesized simultaneously after the second annealing process at 800-850 degrees C. The experiment results suggest that the graphene sheets grow along the nanowires and its crystalline quality and domain size are determined by the temperature and duration of the second annealing process. (C) 2015 Elsevier B.V. All rights reserved.