• 文献标题:   Fast and facile preparation of reduced graphene oxide supported Pt-Co electrocatalyst for methanol oxidation
  • 文献类型:   Article
  • 作  者:   SHEN JF, YAN B, SHI M, MA HW, LI N, YE MX
  • 作者关键词:   composite, nanostructure, chemical synthesi, electrochemical propertie
  • 出版物名称:   MATERIALS RESEARCH BULLETIN
  • ISSN:   0025-5408
  • 通讯作者地址:   Fudan Univ
  • 被引频次:   21
  • DOI:   10.1016/j.materresbull.2012.02.025
  • 出版年:   2012

▎ 摘  要

In this study, we report a scalable, fast, and facile method for preparation of reduced graphene oxide (RGO) sheets supported Pt-Co electrocatalyst for methanol oxidation. Mixed reducing agents were used and the activity of the catalysts was studied. It was found that the presence of RGO leads to higher activity, which might be due to the increasing of electrochemically accessible surface areas and easier charge-transfer at the interfaces. Co can greatly enhance the electrocatalytic activity and moderate the poisoning of Pt catalyst. Under same Pt loading mass and experimental conditions, the RGO-Pt-Co catalyst shows the highest electro catalytic activity and improved resistance to carbon monoxide poisoning among the prepared catalysts. (C) 2012 Elsevier Ltd. All rights reserved.