• 文献标题:   Charge transport in graphene oxide
  • 文献类型:   Review
  • 作  者:   CHANG DW, BAEK JB
  • 作者关键词:   transport of ionic specie, nanofluidic channel, composite electrolyte, mixed proton/electron conductor
  • 出版物名称:   NANO TODAY
  • ISSN:   1748-0132 EI 1878-044X
  • 通讯作者地址:   Ulsan Natl Univ Sci Technol UNIST
  • 被引频次:   9
  • DOI:   10.1016/j.nantod.2017.10.010
  • 出版年:   2017

▎ 摘  要

The transport of ionic species in nano-fluidic channels has recently attracted tremendous interest in various research areas. This is because extraordinary nanoscale transport phenomena have been achieved in these materials, including ultrafast and highly selective ion movement. A variety of organic and inorganic materials have been employed to construct nano-channels or nano-pores with controlled sizes and dimensions. In particular, because of its unique two-dimensional planar architecture, as well as the possession of numerous oxygenated functionalities, GO has emerged as a promising building block for high-performance nano-fluidic ion channels. The simple exfoliation-reconstruction approach can readily assemble individual GO sheets into a free-standing, layered, film-like structure. In addition to its utilization as a versatile solid support for nano-fluidic ion transport, GO can play different but positive roles as a filler in composite electrolytes, as a mixed proton/electron conductor, and as a selective ion permeation membrane. Herein, we summarize the recent advances in the transport of ionic species within GO-based electrolytes. Moreover, the perspectives and current challenges of this promising field are discussed. (C) 2017 Elsevier Ltd. All rights reserved.