• 文献标题:   Monodisperse N-Doped Graphene Nanoribbons Reaching 7.7 Nanometers in Length
  • 文献类型:   Article
  • 作  者:   CORTIZOLACALLE D, MORAFUENTES JP, STRUTYNSKI K, SAEKI A, MELLEFRANCO M, MATEOALONSO A
  • 作者关键词:   graphene, nanoribbon, polycyclic aromatic hydrocarbon
  • 出版物名称:   ANGEWANDTE CHEMIEINTERNATIONAL EDITION
  • ISSN:   1433-7851 EI 1521-3773
  • 通讯作者地址:   Univ Basque Country
  • 被引频次:   20
  • DOI:   10.1002/anie.201710467
  • 出版年:   2018

▎ 摘  要

The properties of graphene nanoribbons are highly dependent on structural variables such as width, length, edge structure, and heteroatom doping. Therefore, atomic precision over all these variables is necessary for establishing their fundamental properties and exploring their potential applications. An iterative approach is presented that assembles a small and carefully designed molecular building block into monodisperse N-doped graphene nanoribbons with different lengths. To showcase this approach, the synthesis and characterisation of a series of nanoribbons constituted of 10, 20 and 30 conjugated linearly-fused rings (2.9, 5.3, and 7.7 nm in length, respectively) is presented.