• 文献标题:   Graphene: Hexagonal Boron Nitride Composite Films with Low-Resistance for Flexible Electronics
  • 文献类型:   Article
  • 作  者:   ANTONOVA IV, SHAVELKINA MB, IVANOV AI, POTERYAEV DA, NEBOGATIKOVA NA, BUZMAKOVA AA, SOOTS RA, KATARZHIS VA
  • 作者关键词:   dc plasma synthesi, composite nanoparticle graphene, hbn, pedot, pss, structure, electric propertie, selforganization effect, inkjet 2d printing technologie
  • 出版物名称:   NANOMATERIALS
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.3390/nano12101703
  • 出版年:   2022

▎ 摘  要

The structure and electric properties of hexagonal boron nitride (h-BN):graphene composite with additives of the conductive polymer PEDOT:PSS and ethylene glycol were examined. The graphene and h-BN flakes synthesized in plasma with nanometer sizes were used for experiments. It was found that the addition of more than 10(-3) mass% of PEDOT:PSS to the graphene suspension or h-BN:graphene composite in combination with ethylene glycol leads to a strong decrease (4-5 orders of magnitude, in our case) in the resistance of the films created from these suspensions. This is caused by an increase in the conductivity of PEDOT:PSS due to the interaction with ethylene glycol and synergetic effect on the composite properties of h-BN:graphene films. The addition of PEDOT:PSS to the h-BN:graphene composite leads to the correction of the bonds between nanoparticles and a weak change in the resistance under the tensile strain caused by the sample bending. A more pronounced flexibility of the composite films with tree components is demonstrated. The self-organization effects for graphene flakes and polar h-BN flakes lead to the formation of micrometer sized plates in drops and uniform-in-size nanoparticles in inks. The ratio of the components in the composite was found for the observed strong hysteresis and a negative differential resistance. Generally, PEDOT:PSS and ethylene glycol composite films are promising for their application as electrodes or active elements for logic and signal processing.